N,N-Diphenyl-4-(1H-pyrrolo[1,2-f][1,10]phenanthrolin-2-yl)aniline ethanol monosolvate
نویسندگان
چکیده
The title compound, C32H21N4·C2H5OH, crystallized as an ethanol monosolvate. In the mol-ecule of this phenanthroline derivative, the pyridine rings are almost coplanar, making a dihedral angle of 1.54 (13)°. The tri-phenyl-amine group, introduced as an electron donor, shows a propeller-type structure, and the dihedral angles between the benzene rings are 68.71 11), 63.92 (16) and 70.81 (15)°. In the crystal, the phenanthroline mol-ecules are linked via the solvent mol-ecule by N-H⋯O, O-H⋯N and C-H⋯O hydrogen bonds, leading to the formation of zigzag chains propagating along [010]. These chains are linked via C-H⋯N hydrogen bonds, forming undulating two-dimensional networks extending in the a- and b-axis directions.
منابع مشابه
[1-(1H-Imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol-κ2 N 7,N 8]diiodidomercury(II)
In the title compound, [HgI(2)(C(23)H(14)N(4)O)], the Hg(II) atom is four-coordinated by two N atoms from one 1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol ligand and by two I atoms in a distorted tetra-hedral environment. An intra-molecular O-H⋯N hydrogen bond stabilizes the mol-ecular conformation and an inter-molecular N-H⋯I inter-action stabilizes the crystal packing.
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عنوان ژورنال:
دوره 69 شماره
صفحات -
تاریخ انتشار 2013